Inorganic Chemistry in Focus III /
Gerd Meyer.
- Germany. : Wiley-VCH Verlag, c2006.
- XLVI, 329.: ill, ; 24 cm.
includes Bibliographical references and Index.
Dedicated. In Praise of Synthesis. Preface. List of Contributors. Biographical Sketches. 1 Inter-electron Repulsion and Irregularities in the Chemistry of Transition Series (David A. Johnson). 1.1 Introduction: Irregularities in Lanthanide Chemistry. 1.2 A General Principle of Lanthanide Chemistry. 1.3 Extensions of the First Part of the Principle. 1.4 Extensions of the Second Part of the Principle. 1.5 The Tetrad Effect. 1.6 The Diad Effect. References. 2 Stereochemical Activity of Lone Pairs in Heavier Main-group Element Compounds (Anja-Verena Mudring). 2.1 Introduction. 2.2 When Does a Lone Pair of Electrons Become Stereochemically Active? - Observations. 2.3 Theoretical Concepts. 2.4 Conclusions. Acknowledgments. References. 3 How Close to Close Packing? (Hideo Imoto). 3.1 Introduction. 3.2 Essential Features of Close Packing. 3.3 Parameter Definitions. 3.4 Correlation Between D and N. 3.5 Transformation of Close-packing Arrangements. 3.6 Close-packing of Cations or of Anions? 3.7 What Determines the Structure? Appendix. ICSD Codes, D and N Parameters of the Structures Used. References. 4 Forty-five Years of Praseodymium Di-iodide, PrI2 (Gerd Meyer and Andriy Palasyuk). Foreword. 4.1 Introduction. 4.2 Phases and Structures in the System Praseodymium-Iodine. 4.3 PrI2: Phases and Phase Analysis. 4.4 Conclusions. Acknowledgments. References. 5 Centered Zirconium Clusters: Mixed-halide Systems (Martin Kockerling). Foreword. 5.1 The Basics of Zirconium Cluster Chemistry. 5.2 Motivation. 5.3 Mixed-Chloride-Iodide Zirconium Cluster Phases with a 6:12-Metal :Halide Ratio. 5.4 Mixed Chloride-Iodide Zirconium Cluster Phases with a 6: 13 Metal :Halide Ratio. 5.5 Mixed Chloride-Iodide Zirconium Cluster Phases with a 6: 14 Metal :Halide Ratio. 5.6 Mixed Chloride-Iodide Zirconium Cluster Phases with a 6: 15 Metal :Halide Ratio. 5.7 Mixed Chloride-Iodide Zirconium Cluster Phases
Metal clusters are on the brink between molecules and nanoparticles in size. With molecular, nano-scale, metallic as well as non-metallic aspects, metal clusters are a growing, interdisciplinary field with numerous potential applications in chemistry, catalysis, materials and nanotechnology. This third volume in the series of hot topics from inorganic chemistry covers all recent developments in the field of metal clusters, with some 20 contributions providing an in-depth view. The result is a unique perspective, illustrating all facets of this interdisciplinary area: Inter-electron Repulsion and Irregularities in the Chemistry of Transition Series; Stereochemical Activity of Lone Pairs in Heavier Main Group Element Compounds; and How Close to Close Packing?; Forty-Five Years of Praseodymium Diiodide; Centered Zirconium Clusters; and Titanium Niobium Oxychlorides Trinuclear Molybdenum and Tungsten Cluster Chalcogenides. It also illustrates: Current State of (B,C,N)-Compounds of Calcium and Lanthanum; Ternary Phases of Lithium with Main-Group and Late-Transition Metals; Polar Intermetallics and Zintl Phases along the Zintl Border; Rare Earth Zintl Phases; Structure-Property Relationships in Intermetallics; Ternary and Quaternary Niobium Arsenide Zintl Phases; The Building Block Approach to Understanding Main-Group-Metal Complex Structures; Cation-Deficient Quaternary Thiospinels; A New Class of Hybrid Materials via Salt Inclusion Synthesis; Layered Perrhenate and Vanadate Hybrid Solids; Hydrogen Bonding in Metal Halides; Syntheses and Catalytic Properties of Titanium Nitride Nanoparticles; Solventless Thermolysis; and New Potential Scintillation Materials in Borophosphate Systems. With its didactical emphasis, this volume addresses a wide readership, such that both students and specialists will profit from the expert contributions.